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Equation (5.3.6) then assumes the form ~ "/Red)]2 (5.3.12) 4ET The general relationship for the activation energy including both the electrode reaction and the chemical redox reaction as derived by Marcus in the form

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The Balanced Scorecard is primarily an agent of change within an organization; a change in the way it measures, in the way it manages, and if utilized effectively, a change in results. As we all know, change can prove to be painfully difficult, so it should come as no surprise that despite the careful foundation poured for the BSC by IS leadership, both core team members and employees were initially hesitant to jump on board. As Scorecard Coordinator Annette Hess explains,

& ^ ^>!

(5 .3. 13 )





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Handling user control events is more or less the same as handling events in any other Web Forms control You need to decide whether to use the event handler in the containing Web Forms page or the user control Writing event handlers in either of the cases is similar However, you need to take some precautions if you decide to include the event handler in the user control For example, if you have included the properties for the control in the existing Web Forms page, the properties will not be accessible from the user control unless you add functionality within the user control Let us create a button and add an event handler to it Consider the user control that you created earlier in the chapter.

Employees were very resistant and reluctant. The BSC was initially perceived as just another flavor of the month that would disappear off the radar in due time. When people realized it was not going away any time soon they began to resist it. Reactions were mixed but mostly staff felt they did not have time for it, they were too busy as it was and this was just another chore piled on top.30

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where vvr and wp are the works required to bring the reactants together and to separate the products and AG is the standard Gibbs energy change for the reaction. For electrode reactions, the quantities wr and wp appear in the effect of the electrical double layer on the rate of the electrode reaction (see Section 5.3.2). If the effect of the electrical double layer is neglected (e.g. at higher indifferent electrolyte concentrations), the rate constant of the cathodic reaction is approximately given by the equation kc = rspa)K exp ( ^

reduced form of the electroactive species, r (rslrs 2)1/2, p is the number of electronic states per unit area in the conductivity band of the electrode, a) is the vibrational frequency of the molecule in the solvation sheath and K is the transmission coefficient, with a value of K ~ 1 for an adiabatic process and K 1 for a non-adiabatic process. As it is assumed that the electron is transferred to a species whose centre lies in the outer Helmholtz plane, the volume concentration of the reactants is converted by the factor 2rs to the surface concentration. The density of the electronic states available for the transfer reaction is estimated as p/2. This is a considerable simplification; in a more exact approach, the quantity p should be multiplied by the Fermi function (Eq. 3.1.10), ^ ( m ) - F0(m) = fie(m) in Eq. (5.3.8) should be replaced by the energy of an electron level e and the whole expression should be integrated with respect to e. However, the more precise solution would not lead to a great improvement because of the great many other simplifications involved in the present treatment. In the same way the equation for the rate constant of the anodic reaction is obtained: (5.3.15) ARTEr J The charge transfer coefficient defined by Eq. (5.2.50) is given with respect to Eq. (5.2.12) as

~ ^Ox/Red)] ]

For some, only proof in the form of results would help sway their sentiments. But for many, simply learning more about the scorecard itself and why IS was launching the initiative proved to be an effective antidote to reluctance and resistance. The IS team communicated to staff in a number of ways: updates and discussions occurred in general department meetings, PowerPoint presentations were delivered, and posters were placed throughout the department highlighting specific aspects of the IS Balanced Scorecard. The IS Strategy Map and Measures Exhibit 5.5 shows the IS department s strategy map of key objectives. The first thing that stands out about their map is that they don t use the four standard Balanced Scorecard perspectives previously discussed. In place of a Financial perspective they ve chosen to use the label Mission and include within it their overall objectives of increasing OCTA value, increasing customer satisfaction, and getting more bang for their buck. Although the standard scorecard monikers have proven effective for many organizations around the globe, they may not match the language many organizations use on a day-to-day basis. To enhance understanding and acceptance of the scorecard, be sure and use perspective titles that fit your IT organization s culture and represent the language spoken by your teams. The IS department also decided to use their four strategic themes as headings with objectives appearing in each of the perspectives telling a

(5.3.16) and is in general not a constant quantity. This is apparent from Fig. 5.7,

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