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The cohesive forces between neighbouring molecules in the liquid phase depend on hydrogen bonds or other 'bridges' (oxygen, halogen), on dipole-dipole interactions or on van der Waals interactions These solvents act as dielectrics and do not appreciably conduct electric current Autoionization occurs to a slight degree in some of them, leading to low electric conductivity (for example 2 H 2 O ^ H 3 O + + OH~; in the melt, 2HgBr2<= HgBr++ HgBr3~; in the liquefied state, 2NO 2 ^ NO + + NO 3 ") Ionic solvents consisting of ions are mostly fused salts However, not all salts yield ions on melting For example, fused HgBr2, POC13, BrF3 and others form molecular liquids On mixing, however, the molecular solvents H2O and H2SO4 can form ionic solvents that contain only the H 3 O + and HSO4~ i n s - Ionic solvents have high ionic electric conductivity.

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Most exist at high temperatures (eg, at normal pressure, NaCl between 800 and 1465 C) but some salts have low melting points (eg ethylpyridinium bromide at -114 C, tetramethylammonium thiocyanate at -505 C) and, in.

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NET, the next generation of Web application technologies Michael started his journey through the technical ranks back in college at the University of Kansas, where he earned his stripes and a couple of degrees After a brief stint as a technical and business consultant to Tokyo-based Global Online Japan, he returned to the States to climb the corporate ladder He has held assorted roles, including those of IT manager, field engineer, trainer, independent consultant, and even a brief stint as Interim CTO of a successful dot-com, although he believes his current role as NET evangelist for Microsoft is the best of the lot He can be reached via e-mail at mlthomas@microsoftcom First and foremost, I want to dedicate this book to my Supreme Guide who has always guided me in the right direction.

14 addition, there is a number of low-melting-point eutectics (for example AICI3 + KC1 + NaCl in a ratio of 60:14:26 mol % melts at 94 C). The ions present in these solvents can be either monoatomic (for example Na+ and Cl~ in fused NaCl) or polyatomic (for example cryolite Na3AlF6 contains Na + , A1F63", AIF4- and F" ions). 1.2.2 Liquid structure

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the right time, forecasts seasonal and business metric saturation points, preempts threshold violations, and creates business metrics. In other words, it helps move IT from stabilization to resource optimization on the maturity scale. Resource Optimization does not, however, measure negotiated service-level agreements. Service Optimization negotiates business application service-level agreements and costs. Because service-level agreements here are expressed in terms of Availability/Response/Throughput, the agreements for each business application greatly depend on how well Resource Optimization measures manage capacity and exceptions. Service Optimization does not measure the effectiveness of capacity forecasting or measure the cost of providing the service. Financial Optimization measures the financial results of the other optimization perspectives plus a few other areas. Here, IT Finance folds into IT strategy and enables the sections to play together symphonically. For purposes of this chapter, Financial Optimization focuses on three key areas: (1) Cost of Business Application Service; (2) Cost of ITIL; and (3) Cost of Infrastructure Capacity. Each of these merges with appropriate results from other optimization suites to give a strategic view of the results.

Molecular liquids are not at all amorphous, as would first appear Methods of structural analysis (X-ray diffraction, NMR, IR and Raman spectroscopy) have demonstrated that the liquid retains the structure of the original crystal to a certain degree Water is the most ordered solvent (and has been investigated most extensively) Under normal conditions, 70 per cent of the water molecules exist in 'ice floes', clusters of about 50 molecules with a structure similar to that of ice and a mean lifetime of 10~ n s Hydrogen bonds lead to intermolecular spatial association Hydrogen bonds are also formed in other solvents, but result in the formation of chains (eg in alcohols) or rings (eg rings containing six molecules are formed in liquid HF).

Thus, the degree of organization is lower in these solvents than in water, although the strength of hydrogen bonds increases in the order: HC1, H2SO4 (practically monomers) < NH3 < H2O < HF Mixing of a highly organized solvent with a less organized one leads to structure modification If, for example, ethanol is added to water, ethanol molecules first enter the water structure and strengthen it; at higher concentrations this order is reversed It is not the purpose of chemistry, but rather of statistical thermodynamics, to formulate a theory of the structure of water Such a theory should be able to calculate the properties of water, especially with regard to their dependence on temperature So far, no theory has been formulated whose equations do not contain adjustable parameters (up to eight in some theories) These include continuum and mixture theories.

Any well-considered, well-managed plan consistent with the complexity of ascending IT maturity indices must set an execution order to the initiatives mandated by the strategy. Similar to PERT charts in project management, strategy maps depict the critical path and relationships between the initiatives. As the strategy is deployed, the strategy map helps identify whether the performance goals are met. Key initiatives that fall behind in attaining goals or targets delay strategic execution. Guiding IT maturity development while learning new applications is a complicated undertaking that requires a strategy map with two separate views. First, Exhibit 4.3 shows the Bottom-Up view of the SAS Governance model; Exhibit 4.4 shows the Top-Down new business application view. Any chaotic, failure-prone IT hardware and software infrastructure is a recipe for poorly played symphonies and the reputations that follow. Accordingly, the first order of business is to put an end to the infrastructure failures. The CIO cannot forecast capacity, define business services, or

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