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Bluebeam Revu · Proprietary, A commercial PDF editor , markup and ... PDF reader, tagger, editor (simple editions) and converter ( free for ... 165 as the procedure following from Eq. (3.1.39) or from Eqs (3.1.45) to (3.1.49). It should be noted that all terms concerning the electrons in the metals as well as those connected with the metals not directly participating in the cell reaction (Pt) have disappeared from the final Eq. (3.1.49). This result is of general significance, i.e. the EMFs of cell reactions involving oxidationreduction processes do not depend on the nature of the metals where those reactions take place. The situation is, of course, different in the case of a metal directly participating in the cell reaction (for example, silver in the above case). For cell reactions in general, both approaches yield the equation for the EMF: RT ln (3.1.60) nr where E is the standard EMF (standard cell reaction potential), n is the charge number and Q is the quotient of the activities of the reactants in the cell reaction raised to the appropriate stoichiometric coefficients; this quotient has the same form as the equilibrium constant of the cell reaction. For practical reasons it is often useful to separate the EMF of a galvanic cell into two terms and assign each of them to one of the electrodes. The half-cell reactions provide a basis for unambiguous separation. The equation for the overall EMF is converted to the difference between two expressions, in which the expression corresponding to the electrode on the left is subtracted from the expression corresponding to the electrode on the right. Thus, for example, it follows for Eq. (3.1.59), with inclusion of a term containing the relative hydrogen pressure, that ^ - ( w ) - RT In qcl-(w) pdf text editor software free download for windows 8 Best PDF editors 2019: Reviewed and rated | PCWorld
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